Promising CL-20-Based Energetic Material by Cocrystallization

被引:90
作者
Anderson, Stephen R. [1 ]
Dube, Pascal [1 ]
Krawiec, Mariusz [1 ]
Salan, Jerry S. [1 ]
Ende, David J. Am [1 ]
Samuels, Philip [2 ]
机构
[1] Nalas Engn Serv Inc, 85 Westbrook Rd, Centerbrook, CT 06409 USA
[2] ARDEC, Picatinny Arsenal, NJ USA
关键词
Cocrystal; CL-20; MDNT; Resonance acoustic mixing; Energetic material; HYDROGEN-BOND; CO-CRYSTALS; SOLID-STATE; HEXANITROHEXAAZAISOWURTZITANE; EXPLOSIVES; STABILITY; CL-20; SENSITIVITY; MECHANISM; DIAGRAMS;
D O I
10.1002/prep.201600065
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A novel cocrystal (NEX-1) of CL-20 and MDNT is presented herein. The CL-20:MDNT cocrystal, obtained in high yield by resonant acoustic mixing, shows new properties versus the discrete components. This is the first example of cocrystallization of CL-20 where the new material is less sensitive to friction than CL-20 itself, while demonstrating similar impact and ESD sensitivity. The CL-20:MDNT cocrystal shows promise in the production of new energetic materials of interest by the cocrystallization of well-characterized components.
引用
收藏
页码:783 / 788
页数:6
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