Structure and properties of an eight-coordinate Mn(II) complex that demonstrates a high water relaxivity

被引：17
|
作者：
Dube, Koustubh S. [1 ]
Harrop, Todd C. [1 ]
机构：
[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA
来源：
DALTON TRANSACTIONS | 2011年 / 40卷 / 29期
关键词：
CRYSTAL-STRUCTURE; MANGANESE(II) COMPLEXES; MAGNETIC-PROPERTIES; TRANSITION-METAL; AGENTS; ACID;
D O I：
10.1039/c1dt10579e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An air-stable eight-coordinate (8C) Mn(II)N-8 complex has been synthesized utilizing an N-4 imidazole/imine ligand. The 8C dodecahedral geometry is structurally robust as the Mn complex is stable to air, NO(g), and potential coordinating anions. The structural, spectroscopic and water relaxivity properties of this complex are reported.
引用
收藏
页码：7496 / 7498
页数：3
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