Heck reaction of β-substituted acrylates in ionic liquids catalyzed by a Pd-benzothiazole carbene complex

被引:111
作者
Calò, V [1 ]
Nacci, A [1 ]
Monopoli, A [1 ]
Lopez, L [1 ]
di Cosmo, A [1 ]
机构
[1] Univ Bari, Dipartmento Chim, Ctr CNR MISO, I-70126 Bari, Italy
关键词
beta-aryl cinnamates; ionic liquids; carbenes; Heck reaction;
D O I
10.1016/S0040-4020(01)00528-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A Pd-catalyst with benzothiazole carbene as ligands allows, in tetrabutylammonium bromide melt as solvent, very fast and efficient reactions of haloaromatics with beta -substituted acrylates. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:6071 / 6077
页数:7
相关论文
共 34 条
[31]   Combining N-heterocyclic carbenes and phosphines:: improved palladium(II) catalysts for aryl coupling reactions [J].
Weskamp, T ;
Böhm, VPW ;
Herrmann, WA .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 585 (02) :348-352
[32]   Heck reaction in ionic liquids and the in situ identification of N-heterocyclic carbene complexes of palladium [J].
Xu, LJ ;
Chen, WP ;
Xiao, JL .
ORGANOMETALLICS, 2000, 19 (06) :1123-1127
[33]  
Yu JQ, 1999, CHEM-EUR J, V5, P2237, DOI 10.1002/(SICI)1521-3765(19990802)5:8<2237::AID-CHEM2237>3.0.CO
[34]  
2-O