A new hydrated sodium vanadium bronze as Li insertion compound

被引：24
作者：
Millet, M
Farcy, J
Pereira-Ramos, JP
Sabbar, EM
De Roy, ME
Besse, JP
机构：
[1] LECSO, CNRS, UM 28, F-94320 Thiais, France
[2] Univ Blaise Pascal, LMI, CNRS, ESA 6002, F-63177 Aubiere, France
来源：
SOLID STATE IONICS | 1998年 / 112卷 / 3-4期
关键词：
Li insertion compound; chronopotentiometric; cyclic voltammetric;
D O I：
10.1016/S0167-2738(98)00202-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A sodium vanadium bronze hydrate, Na0.33V2O5 . 1.3H(2)O has been synthesized from reaction of phosphonic acid with vanadyl ions and sodium hydroxide in aqueous solution. The electrochemical Li insertion has been investigated in this layered structure characterized by a basal spacing of 10.84 Angstrom. Its behaviour differs from that known for the sol-g-el sodium-exchanged V2O5 xerogel and for the anhydrous monoclinic bronze. The presence of water does not hinder Li accommodation and two main reversible insertion steps are found at 3.1 V and 2.65 V for a maximum Li uptake of 1.65 lithium ion per mole of compound. Preliminary chronopotentiometric and cyclic voltammetric experiments indicate the potential interest of such a hydrated vanadium pentoxide bronze for reversible Li insertion reactions. (C) 1998 Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码：319 / 327
页数：9
相关论文
共 27 条
[1]   LAYERED STRUCTURE OF VANADIUM PENTOXIDE GELS [J].
ALDEBERT, P ;
BAFFIER, N ;
GHARBI, N ;
LIVAGE, J .
MATERIALS RESEARCH BULLETIN, 1981, 16 (06) :669-676
[2]   VANADIUM PENTOXIDE ELECTRODES .1. FORMATION OF VANADIUM PENTOXIDE FROM ANODIC ELECTRODEPOSITS [J].
ANDRUKAITIS, E ;
JACOBS, PWM ;
LORIMER, JW .
SOLID STATE IONICS, 1988, 27 (1-2) :19-30
[3]   A THERMODYNAMIC AND KINETIC-STUDY OF ELECTROCHEMICAL LITHIUM INTERCALATION IN NA0.33V2O5 BRONZE PREPARED BY A SOL-GEL PROCESS [J].
BACH, S ;
PEREIRARAMOS, JP ;
BAFFIER, N ;
MESSINA, R .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (04) :1042-1048
[4]   A THERMODYNAMIC, STRUCTURAL AND KINETIC-STUDY OF THE ELECTROCHEMICAL LITHIUM INTERCALATION INTO THE XEROGEL V2O5.1.6 H2O IN A PROPYLENE CARBONATE SOLUTION [J].
BADDOUR, R ;
PEREIRARAMOS, JP ;
MESSINA, R ;
PERICHON, J .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 314 (1-2) :81-101
[5]   SYNTHESIS OF VANADIUM BRONZES BA-2+V2O5, NI-2+V2O5, AL-3+V2O5, FE-3+V2O5 THROUGH SOL-GEL PROCESSES .2. ORTHORHOMBIC BRONZES [J].
BAFFIER, N ;
ZNAIDI, L ;
HUBER, M .
MATERIALS RESEARCH BULLETIN, 1990, 25 (06) :705-713
[6]   Vanadium oxides synthesized using the tetramethylammonium ion: An addendum [J].
Boylan, EA ;
Chirayil, T ;
Hinz, J ;
Zavalij, PY ;
Whittingham, MS .
SOLID STATE IONICS, 1996, 90 (1-4) :1-4
[7]   VANADIUM PENTOXIDE GELS .1. STRUCTURAL STUDY BY ELECTRON-DIFFRACTION [J].
LEGENDRE, JJ ;
LIVAGE, J .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1983, 94 (01) :75-83
[8]  
LEMERLE J, 1978, J CHEM RES, P5301
[9]   VANADIUM PENTOXIDE GELS [J].
LIVAGE, J .
CHEMISTRY OF MATERIALS, 1991, 3 (04) :578-593
[10]   Sol-gel chemistry and electrochemical properties of vanadium oxide gels [J].
Livage, J .
SOLID STATE IONICS, 1996, 86-8 :935-942
123