Enantioselective total synthesis of (-)-equisetin using a Me3Al-mediated intramolecular Diels-Alder reaction

被引：30

作者：

Yuki, K ^{[1
]}

Shindo, M ^{[1
]}

Shishido, K ^{[1
]}

机构：

[1] Univ Tokushima, Inst Med Resources, Tokushima 7708505, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 13期

关键词：

Diels-Alder reactions; stereocontrol; biologically active compounds; polyketides;

D O I：

10.1016/S0040-4039(01)00217-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and enantioselective total synthesis of (-)-equisetin 1 has been accomplished using a diastereoselective Me3Al-mediated intramolecular Diels-Alder (IMDA) reaction as a key reaction step. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2517 / 2519

页数：3

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