Lanthanide Terpyridine-Based Assemblies: Towards Dual Luminescent Probes

被引：4

作者：

Molloy, Jennifer K. ^{[1
]}

Pillai, Zeena ^{[1
]}

Sakamoto, Junji ^{[2
]}

Ceroni, Paola ^{[1
]}

Bergamini, Giacomo ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim, I-40126 Bologna, Italy

[2] ETH, Dept Mat, CH-8093 Zurich, Switzerland

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 4卷 / 03期

关键词：

lanthanides; luminescence; nanoparticles; self-assembly; terpyridines; COMPLEXES; COORDINATION; EMISSION; LIGHT; IONS; DENDRIMER; MICELLES; POLYMERS; LIGANDS; SHEETS;

D O I：

10.1002/ajoc.201402268

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A tetrahedral shape-persistent molecule equipped with four terpyridine ligands can form an oligomeric structure upon complexation with metal ions, in which two terpyridine units are intermolecularly connected via a metal ion. The most interesting results were obtained upon binding of lanthanide ions, whose luminescence is sensitized by the ligand. In particular, dual luminescent probes were obtained upon concomitant complexation of two different lanthanide ions, such as Eu-III and Nd-III.

引用

页码：251 / 255

页数：5

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