Nano CuFe2O4: an efficient, magnetically separable catalyst for transesterification of β-ketoesters

被引：24

作者：

Gohain, Mukut ^{[1
]}

Kumar, Vinod ^{[2
]}

van Tonder, Johannes H. ^{[1
]}

Swart, Hendrik C. ^{[2
]}

Ntwaeaborwa, Odireleng M. ^{[2
]}

Bezuidenhoudt, Barend C. B. ^{[1
]}

机构：

[1] Univ Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa

[2] Univ Free State, Dept Phys, ZA-9300 Bloemfontein, South Africa

来源：

RSC ADVANCES | 2015年 / 5卷 / 24期

关键词：

KETO-ESTERS; VEGETABLE-OILS; 1,3-DICARBONYL COMPOUNDS; ACTIVE METHYLENES; HIGHLY EFFICIENT; NANOPARTICLES; ACID; ALKYLATION; ESTERIFICATION; BIODIESEL;

D O I：

10.1039/c4ra15014g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation of a variety of beta-ketoesters was achieved in high yields from methyl acetoacetate under neutral conditions through the utilization of magnetic CuFe2O4 nanoparticles as catalyst. Recycling of the catalyst was performed up to eight times without significant loss in activity. The catalyst was characterized using XRD, XPS, SEM and TEM techniques.

引用

页码：18972 / 18976

页数：5

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