Photocatalytic reaction of acetaldehyde over SrTiO3 nanoparticles

被引：44

作者：

Chang, Chih-Ang ^{[1
]}

Ray, Brian ^{[1
]}

Paul, Dilip K. ^{[1
]}

Demydov, Drnytro ^{[2
]}

Klabunde, Kenneth J. ^{[2
]}

机构：

[1] Pittsburg State Univ, Dept Chem, Pittsburg, KS 66762 USA

[2] Kansas State Univ, Dept Chem, Manhattan, KS 66506 USA

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2008年 / 281卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

acetaldehyde; FF-IR; SrTiO3; nanoparticles; photooxidation; photocatalytic reaction;

D O I：

10.1016/j.molcata.2007.08.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photooxidation of acetaldehyde on SrTiO3 has been studied using UV-vis irradiation in the range of 2.1-5.0 eV. It has been found that a large fraction of acetaldehyde undergoes aldol condensation during dark oxidation forming crotonaldehyde. However, in presence of UV light, the formation of CO2 and other partially oxidized species was observed. The infrared assignment of surface species was used to explore the photochemical reaction. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：99 / 106

页数：8

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