Adsorption and desorption of Hg(II) from aqueous solution using magnetic Fe3O4@PPy composite microspheres

Functional magnetic Fe3O4@PPy microspheres were prepared and characterized by XRD, FTIR, SEM, TEM, and magnetometer, and the adsorption of Hg(II) onto Fe3O4@PPy was investigated. The results showed that the adsorption of Hg(II) onto Fe3O4@PPy dramatically increases within 5 min and reaches adsorption equilibrium at 200 min. The adsorption of Hg(II) increases with pH increased, and a removal efficiency (RE) of 90.5% was obtained at pH 7.2. The isotherm studies revealed that the adsorption of Hg(II) onto the Fe3O4@PPy fits well with the Langmuir isotherm model, and the calculated q(m) value of 232.56 mg/g. The adsorption process of Hg(II) onto the Fe3O4@PPy is well-fitted by the pseudo-second-order model with a high correlation coefficient (R-2) of 0.999. The thermodynamic coefficients (Delta H degrees, Delta S degrees, and Delta G degrees) were calculated from the temperature-dependent adsorption isotherms and illustrated that the adsorption of Hg(II) on the Fe3O4@PPy was spontaneous and endothermic. Different desorption agents were used to recover Hg(II) adsorbed onto Fe3O4@PPy, and a satisfactory recovery percentage of 93.0% was obtained by using 0.1 M HCl and 0.05 M NaCl.