Nucleophilic addition of triethyl phosphite to acetates of the Baylis-Hillman adducts: Stereoselective synthesis of (E)- and (Z)-allylphosphonates

被引：43
作者：
Basavaiah, D
Pandiaraju, S
机构：
[1] School of Chemistry, University of Hyderabad
来源：
TETRAHEDRON | 1996年 / 52卷 / 06期
关键词：
D O I：
10.1016/0040-4020(95)01055-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Nucleophilic addition of triethyl phosphite to 3-acetoxy-2-methylenealkanenitriles and methyl 3-acetoxy-2-methylenealkanoates provides (2E)-2-(diethoxyphosphorylmethyl)alk-2-enenitriles and methyl (2Z)-2-(diethoxyphosphorylmethyl) alk-2-enoates respectively with good stereoselectivity.
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页码：2261 / 2268
页数：8
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