Inhomogeneity in the interaction between methanol molecules and Bronsted acid sites of H-ZSM-5 directly detected by 2D CPMAS 13C NMR spectroscopy

被引：4

作者：

Inumaru, K ^{[1
]}

Jin, N ^{[1
]}

Uchida, S ^{[1
]}

Misono, M ^{[1
]}

机构：

[1] Univ Tokyo, Dept Appl Chem, Grad Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 14期

关键词：

D O I：

10.1039/a802268b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1D and 2D exchange C-13 NMR investigation of the states of methanol adsorbed on H-ZSM-5 at ambient temperature demonstrates the coexistence of methanol strongly interacting with Bronsted acid sites and methanol physisorbed or hydrogen-bonded, and provides the first spectroscopic evidence of a wide distribution in the strength of its interaction with Bronsted acid sites.

引用

页码：1489 / 1490

页数：2

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