Orthogonal projection approach applied to peak purity assessment

被引：196
作者：
Sanchez, FC [1 ]
Toft, J [1 ]
vandenBogaert, B [1 ]
Massart, DL [1 ]
机构：
[1] FREE UNIV BRUSSELS,CHEMOAC,B-1090 BRUSSELS,BELGIUM
来源：
ANALYTICAL CHEMISTRY | 1996年 / 68卷 / 01期
关键词：
D O I：
10.1021/ac950496g
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The orthogonal projection approach (OPA), a stepwise approach based on an orthogonalization algorithm, is proposed. The performance of OPA for the assessment of peak purity in HPLC-DAD is described and compared with that of SIMPLISMA. The occurrence of artifacts in both approaches under nonideal situations is discussed.
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页码：79 / 85
页数：7
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