1-Disulfo-[2,2-bipyridine]-1,1-diium chloride ionic liquid as an efficient catalyst for the green synthesis of 5-substituted 1 H-tetrazoles

被引：19
作者：
Aali, Elaheh [1 ]
Gholizadeh, Mostafa [1 ]
Noroozi-Shad, Nazanin [1 ]
机构：
[1] Ferdowsi Univ Mashhad, Fac Sci, Dept Chem, Mashhad, Razavi Khorasan, Iran
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2022年 / 1247卷
关键词：
Cycloaddition reaction; 1-Disulfo-[22-bipyridine]-1,1-diium chloride; Ionic liquid; Tetrazoles; 3+2 CYCLOADDITION; 1H-TETRAZOLES; CHEMISTRY; NITRILES; ACID; CONVERSION;
D O I：
10.1016/j.molstruc.2021.131289
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A simple, green and efficient method has been developed for the synthesis of 5-substituted 1H-tetrazole derivatives through [2 + 3] cycloaddition reaction in good to excellent yields between various benzonitriles and sodium azide. For this purpose, 1-disulfo-[2,2-bipyridine]-1,1-diium chloride ([BiPy](HSO3)(2)Cl-2) system as an ionic liquid catalyst have been extended for the construction of these valuable products. This procedure has significant advantages, including using ethylene glycol as a green solvent. The other advantages of this method are inexpensive and ease the preparation of the catalyst, mild reaction conditions, green reaction medium, easy workup, short reaction time, and simple experimental process. (C) 2021 Elsevier B.V. All rights reserved.
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页数：7
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