One-Pot, Bioinspired Coatings To Reduce the Flammability of Flexible Polyurethane Foams

被引:45
作者
Davis, Rick [1 ]
Li, Yu-Chin [1 ]
Gervasio, Michelle [1 ]
Luu, Jason [1 ]
Kim, Yeon Seok [1 ]
机构
[1] NIST, Fire Res Div, Engn Lab, Gaithersburg, MD 20899 USA
关键词
fire retardant; boron; polyurethane foam; biopolymers; one pot; FLAME; FILMS;
D O I
10.1021/acsami.5b01105
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
hi this manuscript, natural materials were combined into a single "pot" to produce flexible, highly fire resistant, and bioinspired coatings on flexible polyurethane foam (PUP). In one step, PUF was coated with a fire protective layer constructed of a polysaccharide binder (starch or agar), a boron fire retardant (boric acid or derivative), and a dirt char former (montmorillonite clay). Nearly all coatings produced,a 63% reduction in a critical flammability value, the peak beat release rate (PHRR). One formulation produced a 75% reduction in PHRR. This technology was validated in full-scale furniture fire tests, where a 75% reduction in PHRR was measured. At these PHRR values, this technology could reduce the fire threat of furniture from significant fire damage in and beyond the room of fire origin to being contained to the burning,furniture. This flammability reduction was caused by three mechanisms-the gas-Phase and condensed-phase processes of the boron the retardant and the condensed-phase process of the clay. We describe the one-pot coating process and the impact of the coating composition on flammability:
引用
收藏
页码:6082 / 6092
页数:11
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