Z-scheme heterojunction through interface engineering for broad spectrum photocatalytic water splitting

被引：80
作者：
Xu, Shu [1 ]
Gong, Shuaiqi [1 ]
Jiang, Hua [1 ]
Shi, Penghui [1 ]
Fan, Jinchen [1 ]
Xu, QunJie [1 ,2 ]
Min, YuLin [1 ,2 ]
机构：
[1] Shanghai Univ Elect Power, Shanghai Key Lab Mat Protect & Adv Mat Elect Powe, Shanghai 200090, Peoples R China
[2] Shanghai Inst Pollut Control & Ecol Secur, Shanghai 200092, Peoples R China
来源：
APPLIED CATALYSIS B-ENVIRONMENTAL | 2020年 / 267卷
基金：
中国国家自然科学基金;
关键词：
Photocatalyst; Z-type heterojunction; NIR light; TUNGSTEN NITRIDE NANOSHEETS; BLACK PHOSPHORUS; HYDROGEN EVOLUTION; CARBON DOTS; ELECTROCATALYST; DEGRADATION; PERFORMANCE; GRAPHENE; OXIDE; WN;
D O I：
10.1016/j.apcatb.2020.118661
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this paper, we have designed the composite material of black phosphorus/tungsten nitride (BP/WN) with near-infrared light (NIR light) response as a noble-metal free photocatalyst for the first time. Modification of bulk BP by ball milling can control the band gap of the composite material to achieve efficient photocatalytic hydrogen evolution in the near-infrared region. At wider than 420 nm, and with illumination wider than 700 nm, a certain amount of hydrogen can be produced without any hole quencher. The rate of photocatalytic hydrogen evolution from pure water reaches 10.77 mu molg(-1)h(-1) under NIR light without any cocatalyst. The presence of a Z-type heterojunction effectively separates photogenerated carriers and prolongs the lifetime of photogenerated carriers, thereby enhancing the photocatalytic performance. The results indicate that BP/WN photocatalysts can provide a new approach to artificial photosynthesis and renewable energy conversion.
引用
收藏
页数：12
相关论文
共 50 条
[31]   Direct Z-Scheme Hetero-phase Junction of Black/Red Phosphorus for Photocatalytic Water Splitting [J].
Liu, Fulai ;
Shi, Rui ;
Wang, Zhuan ;
Weng, Yuxiang ;
Che, Chi-Ming ;
Chen, Yong .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (34) :11791-11795
[32]   Fabrication of Z-scheme heterojunction of UCN/BWO for selective photocatalytic benzylamine oxidation [J].
Xi, Hui ;
Xu, Xueqing ;
Yang, Qian ;
Su, Rui ;
Wang, Hui ;
Li, Deshun ;
Mu, Qiyun ;
Liu, Dan ;
Yang, Zhiwang ;
Lei, Ziqiang .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2024, 697
[33]   The formation of Z-scheme AgI/BiOBr heterojunction and its excellent photocatalytic performance [J].
Qiu, Xiaoyu ;
Li, Jiaming ;
Zhao, Yiyang ;
Lin, Sen ;
Sun, Zhangwei ;
Fang, Yida ;
Guo, Li .
JOURNAL OF ALLOYS AND COMPOUNDS, 2023, 967
[34]   Antibacterial activity of a nonmetal Z-scheme heterojunction photocatalyst [J].
Li, Xuyun ;
Liu, Zhihai ;
Wang, Jing ;
Zhang, Yaru ;
Tang, Haizhong ;
Allardice, Philip James ;
Song, Zuwei ;
Qian, Bei .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2022, 431
[35]   Arsenene/Ti2CO2 Heterojunction as a Promising Z-Scheme Photocatalyst for Overall Water Splitting [J].
Hua, Ling ;
Wang, Youxi ;
Li, Zhenyu .
ADVANCED FUNCTIONAL MATERIALS, 2024, 34 (48)
[36]   In Situ Construction of Direct Z-Scheme Cd0.8Mn0.2S/NiTiO3 Heterojunction for Photocatalytic Overall Water Splitting [J].
Shao, Xinxin ;
Wang, Yanan ;
Xu, Jiapeng ;
Li, Renjie ;
Peng, Tianyou .
ENERGY & FUELS, 2025, 39 (04) :2203-2215
[37]   Weakness-complementing Z-scheme black phosphorus/TiO2 heterojunction with efficient charge separation and photocatalytic overall water splitting activity [J].
Zhou, Xiaosong ;
Liang, Jiabao ;
Xu, Limei ;
Wu, Siyu ;
Xie, Minyi ;
Liang, Qiongdan ;
Luo, Jin ;
Fan, Xuliang ;
Zhou, Xunfu ;
Zhou, Xiaoqin .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2025, 689
[38]   Designing SnS/MoS2 van der Waals heterojunction for direct Z-scheme photocatalytic overall water-splitting by DFT investigation [J].
Jia, Xiaofang ;
Wang, Jinlong ;
Lu, Yue ;
Sun, Jiaming ;
Li, Yang ;
Wang, Yuyan ;
Zhang, Junying .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2022, 24 (35) :21321-21330
[39]   Two-dimensional C3N/WS2 vdW heterojunction for direct Z-scheme photocatalytic overall water splitting [J].
Li, Haotian ;
Xu, Liang ;
Huang, Xin ;
Ou-Yang, Jie ;
Chen, Min ;
Zhang, Ying ;
Tang, Shuaihao ;
Dong, Kejun ;
Wang, Ling-Ling .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2023, 48 (06) :2186-2199
[40]   Direct Z-scheme arsenene/HfS2 van der Waals heterojunction for overall photocatalytic water splitting: First-principles study [J].
Zhu, Xue Ting ;
Xu, Ying ;
Cao, Yong ;
Zou, Dai Feng ;
Sheng, Wei .
APPLIED SURFACE SCIENCE, 2022, 574
12345