A new mixed ligand based Cd(II) 2D coordination polymer with functional sites: Photoluminescence and photocatalytic properties

被引：26

作者：

Cai, Shu-Lan ^{[1
]}

Lu, Lu ^{[1
]}

Wu, Wei-Ping ^{[1
]}

Wang, Jun ^{[1
]}

Sun, Yan-Chun ^{[1
]}

Ma, Ai-Qing ^{[2
]}

Singh, Amita ^{[3
]}

Kumar, Abhinav ^{[3
]}

机构：

[1] Sichuan Univ Sci & Engn, Sch Chem & Environm Engn, Zigong, Peoples R China

[2] Guangdong Med Univ, Dongguan Key Lab Drug Design & Formulat Technol, Key Lab Res & Dev New Med Mat, Sch Pharm, Dongguan 523808, Peoples R China

[3] Univ Lucknow, Fac Sci, Dept Chem, Lucknow 226007, Uttar Pradesh, India

来源：

INORGANICA CHIMICA ACTA | 2019年 / 484卷

关键词：

Coordination polymers; Luminescence; Photocatalysis; DOS; METAL-ORGANIC FRAMEWORKS; LUMINESCENT; DEGRADATION; ADSORPTION; EXPLOSIVES; REMOVAL; SENSOR; SERIES; ENHANCEMENT; DIVERSITY;

D O I：

10.1016/j.ica.2018.09.066

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solvothermal reaction of Cd(OAc)(2)center dot H2O with 5-(4-carboxyphenoxy)isophthalic acid (H3L) as ligand and 3,3',5,5'-tetramethyl-4,4'-bipyrazole (bpz) as co-ligand afforded a new coordination polymer [Cd(L)(Hbpz)](n) (1), which was characterized. Compound 1 shows 2D layer network which can work as highly sensitive sensor to detect Fe3+ by the decrease in its luminescence intensity because of the existence of active sites. The photocatalytic activity towards the degradation of methyl violet (MV) in polluted water was explored. In addition, the photocatalytic activity of 1 against the photodecomposition of organic dye has been addressed using density of states (DOS) calculations.

引用

页码：291 / 296

页数：6

共 51 条

[11] Metal-organic frameworks based on naphthalene-1,5-diyldioxy-di-acetate: structures, topologies, photoluminescence and photocatalytic properties [J].

Gong, Yun ;

Wu, Tao ;

Lin, JianHua .

CRYSTENGCOMM, 2012, 14 (10) :3727-3736

[12] Synthesis, structural versatility and magnetic properties of a series of copper(II) coordination polymers based on bipyrazole and various dicarboxylate ligands [J].

Han, Lu-Lu ;

Wang, Su-Na ;

Jaglicic, Zvonko ;

Zeng, Su-Yuan ;

Zheng, Jun ;

Li, Zhong-Hui ;

Chen, Jiang-Shan ;

Sun, Di .

CRYSTENGCOMM, 2015, 17 (06) :1405-1415

[13] Sorption Properties and Nitroaromatic Explosives Sensing Based on Two Isostructural Metal-Organic Frameworks [J].

He, Hongming ;

Song, Yang ;

Sun, Fuxing ;

Zhao, Nian ;

Zhu, Guangshan .

CRYSTAL GROWTH & DESIGN, 2015, 15 (04) :2033-2038

[14] Design and solvothermal synthesis of luminescent copper(I)-pyrazolate coordination oligomer and polymer frameworks [J].

He, Jun ;

Yin, Ye-Gao ;

Wu, Tao ;

Li, Dan ;

Huang, Xiao-Chun .

CHEMICAL COMMUNICATIONS, 2006, (27) :2845-2847

[15] Four Co(II) coordination polymers based on 4,4′-bis(benzimidazol-1-ylmethyl)biphenyl and aromatic carboxylic acids co-ligands: Synthesis, structures, and photocatalytic properties [J].

Hu, Ju-Meng ;

Guo, Rui ;

Liu, Yong-Guang ;

Cui, Guang-Hua .

INORGANICA CHIMICA ACTA, 2016, 450 :418-425

[16] Effective Detection of Mycotoxins by a Highly Luminescent Metal-Organic Framework [J].

Hu, Zhichao ;

Lustig, William P. ;

Zhang, Jingming ;

Zheng, Chong ;

Wang, Hao ;

Teat, Simon J. ;

Gong, Qihan ;

Rudd, Nathan D. ;

Li, Jing .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (51) :16209-16215

[17] A new Zn(II) metal-organic framework having 3D CdSO4 topology as luminescent sensor and photocatalyst for degradation of organic dyes [J].

Jin, Jun-Cheng ;

Wu, Jian ;

Liu, Wei-Cong ;

Ma, Ai-Qing ;

Liu, Jian-Qiang ;

Singh, Amita ;

Kumar, Abhinav .

NEW JOURNAL OF CHEMISTRY, 2018, 42 (04) :2767-2775

[18] Two porous luminescent metal-organic frameworks: quantifiable evaluation of dynamic and static luminescent sensing mechanisms towards Fe3+ [J].

Jin, Jun-Cheng ;

Pang, Ling-Yan ;

Yang, Guo-Ping ;

Hou, Lei ;

Wang, Yao-Yu .

DALTON TRANSACTIONS, 2015, 44 (39) :17222-17228

[19] Simple and Compelling Biomimetic Metal-Organic Framework Catalyst for the Degradation of Nerve Agent Simulants [J].

Katz, Michael J. ;

Mondloch, Joseph E. ;

Totten, Ryan K. ;

Park, Jin K. ;

Nguyen, SonBinh T. ;

Farha, Omar K. ;

Hupp, Joseph T. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (02) :497-501

[20] DEVELOPMENT OF THE COLLE-SALVETTI CORRELATION-ENERGY FORMULA INTO A FUNCTIONAL OF THE ELECTRON-DENSITY [J].

LEE, CT ;

YANG, WT ;

PARR, RG .

PHYSICAL REVIEW B, 1988, 37 (02) :785-789

← 1 2 3 4 5 6 →