Three-component oxysulfenydation reaction: two simple and convenient approaches to β-alkoxy sulfides

被引：24

作者：

Wang, Dingyi ^{[1
]}

Zhang, Rongxing ^{[1
]}

Ning, Wei ^{[1
]}

Yan, Zhaohua ^{[1
]}

Lin, Sen ^{[1
]}

机构：

[1] Nanchang Univ, Coll Chem, Nanchang 330031, Jiangxi, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2016年 / 14卷 / 22期

基金：

中国国家自然科学基金;

关键词：

BOND FORMATION SYNTHESIS; S BOND; ROOM-TEMPERATURE; ARYLSULFINIC ACIDS; ARYL SULFIDES; IODINE; ALKENES; WATER; CLEAVAGE; ALCOHOLS;

D O I：

10.1039/c6ob00646a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An unprecedented method for the synthesis of beta-alkoxy sulfides via a Nal/HBr-mediated three-component oxysulfenylation reaction of alkenes with arylsulfinic acids and alcohols is reported. Furthermore, I-2-promoted oxysulfenylation of alkenes using sodium arylsulfinates instead of arylsulfinic acids to synthesise various beta-alkoxy sulfides is also described.

引用

页码：5136 / 5140

页数：5

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