Three-component oxysulfenydation reaction: two simple and convenient approaches to β-alkoxy sulfides

被引：24
|
作者：
Wang, Dingyi [1 ]
Zhang, Rongxing [1 ]
Ning, Wei [1 ]
Yan, Zhaohua [1 ]
Lin, Sen [1 ]
机构：
[1] Nanchang Univ, Coll Chem, Nanchang 330031, Jiangxi, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2016年 / 14卷 / 22期
基金：
中国国家自然科学基金;
关键词：
BOND FORMATION SYNTHESIS; S BOND; ROOM-TEMPERATURE; ARYLSULFINIC ACIDS; ARYL SULFIDES; IODINE; ALKENES; WATER; CLEAVAGE; ALCOHOLS;
D O I：
10.1039/c6ob00646a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An unprecedented method for the synthesis of beta-alkoxy sulfides via a Nal/HBr-mediated three-component oxysulfenylation reaction of alkenes with arylsulfinic acids and alcohols is reported. Furthermore, I-2-promoted oxysulfenylation of alkenes using sodium arylsulfinates instead of arylsulfinic acids to synthesise various beta-alkoxy sulfides is also described.
引用
收藏
页码：5136 / 5140
页数：5
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