Novel zirconium complexes derived from C-2-symmetric diamide ligands; The X-ray crystal structure of [Zr(eta(1)-CH(2)Ph)(eta(2)-CH(2)Ph){(C6H3)(2)-2,2'-(NCH(2)C(6)H(4)Ph-4)(2)-6,6'-Me(2)}]

被引：124
作者：
Cloke, FGN
Geldbach, TJ
Hitchcock, PB
Love, JB
机构：
[1] Sch. of Chem. and Molecular Sciences, University of Sussex
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 506卷 / 1-2期
关键词：
zirconium; diamide ligands; olefin polymerization; catalyses; crystal structure;
D O I：
10.1016/0022-328X(95)05913-A
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The novel alkene polymerisation cocatalysts [Zr(CH(2)Ph)(2)(ArDABP)] containing the biphenyl-bridged ligands 2,2'-di-(N-benzyl)amino-6,6'-dimethylbiphenyl (ArDABP, Ar = CH(2)C(6)H(4)(t)Bu-4 or CH2C6H4-Ph) display averaged C-2-symmetry in solution and an eta(2)-benzyl coordination mode in the solid state.
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页码：343 / 345
页数：3
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