Self-assembly of triatomic gold units as supporting frames for a large gold diphenylphosphinite cage molecule

被引：36

作者：

Hollatz, C ^{[1
]}

Schier, A ^{[1
]}

Riede, J ^{[1
]}

Schmidbaur, H ^{[1
]}

机构：

[1] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 02期

关键词：

D O I：

10.1039/a808570f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel hexanuclear cage-type double-decker cation [FB(OPPh2Au)(3)Cl-3(AuPPh2O)(3)BF](+) is obtained in high yield as the tetrafluoroborate salt from a dinuclear diphenylphosphinous acid complex [Ph2P(OH)AuCl](2) upon treatment with BF3. OEt2.

引用

页码：111 / 113

页数：3

共 24 条

[1] 2-COORDINATE AND 4-COORDINATE GOLD(I) COMPLEXES OF TRIS(2-(DIPHENYLPHOSPHINO)ETHYL)PHOSPHINE
BALCH, AL
FUNG, EY
[J]. INORGANIC CHEMISTRY, 1990, 29 (23) : 4764 - 4768
[2] Synthesis and structure of binuclear single-bridged bis[(phosphane)gold(I)]halogenonium complexes
Bayler, A
Bauer, A
Schmidbaur, H
[J]. CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (01): : 115 - 118
[3] Crystal engineering and organometallic architecture
Braga, D
Grepioni, F
Desiraju, GR
[J]. CHEMICAL REVIEWS, 1998, 98 (04) : 1375 - 1405
[4] SPECTROSCOPY, PHOTOREDOX PROPERTIES AND X-RAY CRYSTAL-STRUCTURES OF TRIANGULAR GOLD(I) AND SILVER(I) PHOSPHINE COMPLEXES
CHE, CM
YIP, HK
YAM, VWW
CHEUNG, PY
LAI, TF
SHIEH, SJ
PENG, SM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (03): : 427 - 433
[5] 1,1'-BIS(DIPHENYLPHOSPHINO)BICYCLOPROPYL - SYNTHESIS, PROPERTIES, PRECURSORS, DERIVATIVES, AND METAL-COMPLEXES
DZIWOK, K
LACHMANN, J
WILKINSON, DL
MULLER, G
SCHMIDBAUR, H
[J]. CHEMISCHE BERICHTE, 1990, 123 (03) : 423 - 431
[6] ELECTRON-DEFICIENT BONDING AT PENTACOORDINATE NITROGEN
GROHMANN, A
RIEDE, J
SCHMIDBAUR, H
[J]. NATURE, 1990, 345 (6271) : 140 - 142
[7] Auracarboranes with and without Au-Au interactions: An unusually strong aurophilic interaction
Harwell, DE
Mortimer, MD
Knobler, CB
Anet, FAL
Hawthorne, MF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (11) : 2679 - 2685
[8] Self-assembly of tripodal tris(diphenylphosphinito)fluoroborate ligands in trinuclear gold(I) complexes
Hollatz, C
Schier, A
Schmidbaur, H
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 1998, 1 (03) : 115 - 117
[9] Aggregation of a neutral gold(I) complex through cooperative action of hydrogen bonding and auriophilicity
Hollatz, C
Schier, A
Schmidbaur, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (34) : 8115 - 8116
[10] JOHNSON CK, 1997, ORNL5138

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