Self-assembly of triatomic gold units as supporting frames for a large gold diphenylphosphinite cage molecule

被引:36
|
作者
Hollatz, C [1 ]
Schier, A [1 ]
Riede, J [1 ]
Schmidbaur, H [1 ]
机构
[1] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany
关键词
D O I
10.1039/a808570f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel hexanuclear cage-type double-decker cation [FB(OPPh2Au)(3)Cl-3(AuPPh2O)(3)BF](+) is obtained in high yield as the tetrafluoroborate salt from a dinuclear diphenylphosphinous acid complex [Ph2P(OH)AuCl](2) upon treatment with BF3. OEt2.
引用
收藏
页码:111 / 113
页数:3
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