Vanadium Oxide Nanotube Spherical Clusters Prepared on Carbon Fabrics for Energy Storage Applications

被引:81
作者
Perera, Sanjaya D.
Patel, Bijal
Bonso, Jeliza
Grunewald, Max
Ferraris, John P.
Balkus, Kenneth J., Jr. [1 ]
机构
[1] Univ Texas Dallas, Dept Chem, Richardson, TX 75080 USA
关键词
V2O5; nanotubes; nanotube spherical clusters; nanourchins; pulsed laser deposition; supercapacitors; PULSED-LASER DEPOSITION; V2O5; THIN-FILMS; VOX NANOTUBES; GROWTH; INTERCALATION; ELECTRODES; MICROSTRUCTURE; PERFORMANCE; COMPOSITES; INSERTION;
D O I
10.1021/am2011965
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Vanadium oxide nanotubes have shown great promise as electrode materials for energy storage devices. In this study, we report the synthesis of V2O5 nanotube (VNT) clusters, which form densely packed radial arrangements of VNTs on high-surface-area carbon fiber fabrics (CF). This was achieved by coating the CF with V2O5 by pulsed laser deposition (PLD). Hydrothermal treatment of the PLD films in the presence of excess intercalated V2O5 results in formation of well-adhered VNT clusters on the CF. The densely packed VNTs have inner and outer diameters and interlayer distances of similar to 24, similar to 70, and similar to 2.4 nm, respectively. Coin cell type supercapacitors (CR2032) were assembled using VNT-CF material and electrochemical properties were evaluated.
引用
收藏
页码:4512 / 4517
页数:6
相关论文
共 50 条
[1]   Synthesis of vanadium oxide nanotubes via an ultrasonic method [J].
Ahmad, A. L. ;
Koohestani, B. ;
Bhatia, S. ;
Ooi, B. S. .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2010, 56 (03) :327-332
[2]   Vanadium Pentoxide Nanostructures: An Effective Control of Morphology and Crystal Structure in Hydrothermal Conditions [J].
Avansi, Waldir, Jr. ;
Ribeiro, Caue ;
Leite, Edson R. ;
Mastelaro, Valmor R. .
CRYSTAL GROWTH & DESIGN, 2009, 9 (08) :3626-3631
[3]   Preparation of partially oriented zeolite MCM-22 membranes via pulsed laser deposition [J].
Balkus, KJ ;
Gbery, G ;
Deng, ZS .
MICROPOROUS AND MESOPOROUS MATERIALS, 2002, 52 (03) :141-150
[4]   Highly oriented V2O5 nanocrystalline thin films by plasma-enhanced chemical vapor deposition [J].
Barreca, D ;
Armelao, L ;
Caccavale, F ;
Di Noto, V ;
Gregori, A ;
Rizzi, GA ;
Tondello, E .
CHEMISTRY OF MATERIALS, 2000, 12 (01) :98-103
[5]  
Bonso J. S., 2011, J POWER SOURCES
[6]   Growth of nanotubes in sol-gel-derived V2O5 powders and films prepared under acidic conditions [J].
Ceccato, R. ;
Dire, S. ;
Barone, T. ;
De Santo, G. ;
Cazzanelli, E. .
JOURNAL OF MATERIALS RESEARCH, 2009, 24 (02) :475-481
[7]   Fast, completely reversible Li insertion in vanadium pentoxide nanoribbons [J].
Chan, Candace K. ;
Peng, Hailin ;
Twesten, Ray D. ;
Jarausch, Konrad ;
Zhang, Xiao Feng ;
Cui, Yi .
NANO LETTERS, 2007, 7 (02) :490-495
[8]   Investigations on capacitive properties of the AC/V2O5 hybrid supercapacitor in various aqueous electrolytes [J].
Chen, Lian-Mei ;
Lai, Qiong-Yu ;
Hao, Yan-Jing ;
Zhao, Yan ;
Ji, Xiao-Yang .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 467 (1-2) :465-471
[9]   Design and Synthesis of Hierarchical Nanowire Composites for Electrochemical Energy Storage [J].
Chen, Zheng ;
Qin, Yaochun ;
Weng, Ding ;
Xiao, Qiangfeng ;
Peng, Yiting ;
Wang, Xiaolei ;
Li, Hexing ;
Wei, Fei ;
Lu, Yunfeng .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (21) :3420-3426
[10]   Graphene and nanostructured MnO2 composite electrodes for supercapacitors [J].
Cheng, Qian ;
Tang, Jie ;
Ma, Jun ;
Zhang, Han ;
Shinya, Norio ;
Qin, Lu-Chang .
CARBON, 2011, 49 (09) :2917-2925