Hydrocarbons Production from m-Cresol as a Lignin Model Compound Over Nickel Silicate Catalysts

被引:3
作者
Lee, Heejin [1 ]
Cho, Eun-Bum [2 ]
Jung, Sang-Chul [3 ]
Kim, Sang Chai [4 ]
Park, Young-Kwon [1 ]
机构
[1] Univ Seoul, Sch Environm Engn, Seoul 02504, South Korea
[2] Seoul Natl Univ Sci & Technol, Dept Fine Chem, Seoul 01811, South Korea
[3] Sunchon Natl Univ, Dept Environm Engn, Sunchon 57922, South Korea
[4] Mokpo Natl Univ, Dept Environm Educ, Mokpo 58554, South Korea
基金
新加坡国家研究基金会;
关键词
Hydrodeoxygenation (HDO); m-Cresol; Nickel Silicate; Catalyst; Bio-Oil; PYROLYSIS BIO-OIL; HYDRODEOXYGENATION; GUAIACOL; BIOMASS;
D O I
10.1166/jnn.2020.17640
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydrodeoxygenation (HDO) reactions under low/atmospheric pressure of hydrogen should be studied to solve the problem of the economics of the high-pressure hydrogen upgrading process. Therefore, in this study, the catalytic HDO reaction of m-cresol in atmospheric hydrogen pressure was evaluated using Ni/silica and Nickel silicate (Ni-MCM-41) catalysts. The Ni-MCM-41 catalyst exhibited higher conversion of m-cresol than Ni/silica. The high activity of the Ni-MCM-41 catalyst was due to the large specific surface area and the high nickel loading.
引用
收藏
页码:5738 / 5741
页数:4
相关论文
共 33 条
[21]   Process Simulation and Economic Feasibility of Upgraded Biooil Production Plant from Sawdust [J].
Oh, Chang-Ho ;
Lim, Young-Il .
KOREAN CHEMICAL ENGINEERING RESEARCH, 2018, 56 (04) :496-523
[22]   Co-pyrolytic behaviors of biomass and polystyrene: Kinetics, thermodynamics and evolved gas analysis [J].
Ozsin, Gamzenur ;
Putun, Ayse Eren .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2018, 35 (02) :428-437
[23]   Facile One-Pot Synthesis of Yolk-Shell Structured Ni Doped Mesoporous Silica and Its Application in Enzyme-Free Glucose Sensor [J].
Pal, Nabanita ;
Banerjee, Sangam ;
Choi, Eunji ;
Cho, Eun-Bum .
CHEMISTRYSELECT, 2018, 3 (22) :6029-6034
[24]   Pyrolysis of Waste Oriental Medicine Byproduct Obtained from the Decoction Process of Achyranthes Root [J].
Park, Ji Hui ;
Jeong, JaeHun ;
Lee, Ji Young ;
Kim, Young-Min ;
Park, Young-Kwon .
APPLIED CHEMISTRY FOR ENGINEERING, 2018, 29 (04) :474-478
[25]   Catalytic Hydrodeoxygenation of Cork Oak Pyrolysis Oil Over Ni/Al-MCM-41 [J].
Park, Young-Kwon ;
Lee, Heejin ;
Kim, Young-Min .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2019, 19 (02) :1158-1161
[26]   Atmospheric hydrodeoxygenation of bio-oil oxygenated model compounds: A review [J].
Pourzolfaghar, Hamed ;
Abnisa, Faisal ;
Daud, Wan Mohd Ashri Wan ;
Aroua, Mohamed Kheireddine .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2018, 133 :117-127
[27]   Stearic acid hydrodeoxygenation over Pd nanoparticles embedded in mesoporous hypercrosslinked polystyrene [J].
Sapunov, Valentin N. ;
Stepacheva, Antonina A. ;
Sulman, Esther M. ;
Warna, Johan ;
Maki-Arvela, Paivi ;
Sulman, Mikhail G. ;
Sidorov, Alexander I. ;
Stein, Barry D. ;
Murzin, Dmitry Yu. ;
Matveeva, Valentina G. .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2017, 46 :426-435
[28]  
Shafaghat H., 2015, RSC ADV, V5
[29]   Catalytic hydrodeoxygenation of simulated phenolic bio-oil to cycloalkanes and aromatic hydrocarbons over bifunctional metal/acid catalysts of Ni/HBeta, Fe/HBeta and NiFe/HBeta [J].
Shafaghat, Hoda ;
Rezaei, Pouya Sirous ;
Daud, Wan Mohd Ashri Wan .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2016, 35 :268-276
[30]   Catalytic Pyrolysis of Waste Paper Cup Containing Coffee Residuals [J].
Shin, Dongik ;
Jeong, Seokmin ;
Kim, Young-Min ;
Lee, Hyung Won ;
Park, Young-Kwon .
APPLIED CHEMISTRY FOR ENGINEERING, 2018, 29 (02) :248-251