Ruthenium(II) complexes for two-photon absorption-based optical power limiting

被引：52

作者：

Girardot, Camille ^{[1
]}

Cao, Bertrand ^{[4
,5
]}

Mulatier, Jean-Christophe ^{[1
]}

Baldeck, Patrice L. ^{[2
]}

Chauvin, Jerome ^{[3
]}

Riehl, Didier ^{[4
]}

Delaire, Jacques A. ^{[5
]}

Andraud, Chantal ^{[1
]}

Lemercier, Gilles ^{[1
]}

机构：

[1] Univ Lyon, CNRS 5182, Ecole Normale Super Lyon, Chim Lab, F-69364 Lyon 07, France

[2] Univ Grenoble 1, CNRS 5588, Spectrometrie Phys Lab, F-38402 St Martin Dheres, France

[3] Univ Grenoble 1, CNRS 5250, ICMG, FR 2607,Dept Chim Mol, F-38402 St Martin Dheres, France

[4] Ctr Expertise Parisien, F-94114 Arcueil, France

[5] Ecole Normale Super, CNRS, UMR 8531, Lab Photophys & Photochim Supramol & Macromol, F-94235 Cachan, France

来源：

CHEMPHYSCHEM | 2008年 / 9卷 / 11期

关键词：

absorption; charge transfer; optical power limiting; ruthenium; two-photon absorption;

D O I：

10.1002/cphc.200800186

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Long-lived excitation: Novel bifluorene-substituted 1,10-phenanthroline- based RuII coordination complexes are presented (see picture). They fulfil several requirements for optimized optical power limiting in the visible-NIR, as they are stable, soluble and transparent at low laser fluences. The two-photon absorption of these complexes are strongly related to those of the ligand. (Chemical Equation Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1531 / 1535

页数：5

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