Large-scale synthesis of nitrogen-rich carbon nitride microfibers by using graphitic carbon nitride as precursor

被引：253

作者：

Zhao, Yuanchun ^{[1
,4
]}

Liu, Zheng ^{[1
,4
]}

Chu, Weiguo ^{[1
]}

Song, Li ^{[2
]}

Zhang, Zengxing ^{[2
]}

Yu, Dongli ^{[3
]}

Tian, Yongjun ^{[3
]}

Xie, Sishen ^{[2
]}

Sun, Lianfeng ^{[1
,3
]}

机构：

[1] Natl Ctr Nanosci & Technol, Beijing 100080, Peoples R China

[2] Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China

[3] Yanshan Univ, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China

[4] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 09期

关键词：

D O I：

10.1002/adma.200702230

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One-dimensional structures of nitrogen-rich carbon nitride are synthesized via a thermal evaporation process. The C-N atomic rings (s-triazine and/or tri-s-triazine) present in the precursor remain stable during the thermal evaporation and vapor transfer. They act as basic building blocks during the microstructure assembly; thus ensuring a high nitrogen content in the final product.

引用

页码：1777 / +

页数：6

共 28 条

[1] Production and characterisation of vapour grown carbon fiber/polypropylene composites [J].

Brandl, W ;

Marginean, G ;

Chirila, V ;

Warschewski, W .

CARBON, 2004, 42 (01) :5-9

[2] Synthesis of carbon nitride nanotubes via a catalytic-assembly solvothermal route [J].

Cao, CB ;

Huang, FL ;

Cao, CT ;

Li, J ;

Zhu, H .

CHEMISTRY OF MATERIALS, 2004, 16 (25) :5213-5215

[3] Historical developments and new trends in tribological and solid lubricant coatings [J].

Donnet, C ;

Erdemir, A .

SURFACE & COATINGS TECHNOLOGY, 2004, 180 :76-84

[4] Chemical synthesis of mesoporous carbon nitrides using hard templates and their use as a metal-free catalyst for friedel-crafts reaction of benzene [J].

Goettmann, Frederic ;

Fischer, Anna ;

Antonietti, Markus ;

Thomas, Arne .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (27) :4467-4471

[5] Synthesis of g-C3N4 nanoparticles in mesoporous silica host matrices [J].

Groenewolt, M ;

Antonietti, M .

ADVANCED MATERIALS, 2005, 17 (14) :1789-+

[6] Synthesis of carbon nitrides with graphite-like or onion-like lamellar structures via a solvent-free route at low temperatures [J].

Guo, QX ;

Yang, Q ;

Yi, CQ ;

Zhu, L ;

Xie, Y .

CARBON, 2005, 43 (07) :1386-1391

[7] Synthesis of carbon nitride nanotubes with the C3N4 stoichiometry via a benzene-thermal process at low temperatures [J].

Guo, QX ;

Xie, Y ;

Wang, XJ ;

Zhang, SY ;

Hou, T ;

Lv, SC .

CHEMICAL COMMUNICATIONS, 2004, (01) :26-27

[8] Preparation of nitrogen-rich nanolayered, nanoclustered, and nanodendritic carbon nitrides [J].

Huynh, MHV ;

Hiskey, MA ;

Archuleta, JG ;

Roemer, EL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (05) :737-739

[9] Melem (2,5,8-triamino-tri-s-triazine), an important intermediate during condensation of melamine rings to graphitic carbon nitride:: Synthesis, structure determination by X-ray powder diffractometry, solid-state NMR, and theoretical studies [J].

Jürgens, B ;

Irran, E ;

Senker, J ;

Kroll, P ;

Müller, H ;

Schnick, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (34) :10288-10300

[10] Powder synthesis and characterization of amorphous carbon nitride [J].

Khabashesku, VN ;

Zimmerman, JL ;

Margrave, JL .

CHEMISTRY OF MATERIALS, 2000, 12 (11) :3264-3270

← 1 2 3 →