The two spin states of an end-on copper(II)-superoxide mimic

被引：23

作者：

Askari, Mohammad S. ^{[1
]}

Girard, Brigitte ^{[1
]}

Murugesu, Muralee ^{[2
]}

Ottenwaelder, Xavier ^{[1
]}

机构：

[1] Concordia Univ, Dept Chem & Biochem, Montreal, PQ H4B 1R6, Canada

[2] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 28期

基金：

加拿大自然科学与工程研究理事会;

关键词：

COPPER-DIOXYGEN ADDUCT; ALLYLIC AMINATION; TRIS(2-DIMETHYLAMINOETHYL)AMINE ME(6)TREN; MOLECULAR-STRUCTURE; REVERSIBLE BINDING; COMPLEX; REACTIVITY; LIGAND; CRYSTAL; SYSTEMS;

D O I：

10.1039/c1cc11381j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of nitrosobenzene with copper(I) complexes of a tetradentate ligand led to two novel species that are best described as copper(II) complexes of an O-bonded nitrosobenzyl radical anion, in either the singlet or the triplet spin-state. Both states were characterized by crystal structures, magnetic measurements and DFT calculations.

引用

页码：8055 / 8057

页数：3

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