Adsorption and corrosion inhibiting behavior of Lannea coromandelica leaf extract on mild steel corrosion

被引:138
作者
Muthukrishnan, P. [1 ]
Jeyaprabha, B. [2 ]
Prakash, P. [1 ]
机构
[1] Thiagarajar Coll, Dept Chem, Madurai 625009, Tamil Nadu, India
[2] Fatima Michael Coll Engn & Technol, Dept Civil Engn, Madurai 625020, Tamil Nadu, India
关键词
Mild steel; Lannea coromandelica; SEM; AFM; Polarization; Acid corrosion; COLD-ROLLED STEEL; LOW-CARBON STEEL; HYDROCHLORIC-ACID; THERMODYNAMIC CHARACTERIZATION; AQUEOUS EXTRACT; GREEN; DERIVATIVES; SURFACE; COPPER; FRUIT;
D O I
10.1016/j.arabjc.2013.08.011
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Lannea coromandelica leaf extract (LCLE) as a corrosion inhibitor in 1 M H2SO4 was investigated by weight loss and electrochemical techniques. Inhibition efficiency of LCLE was found to increase with increasing concentration but decreased with increasing temperature. Polarization measurements revealed that the LCLE acted as a mixed type inhibitor. Nyquist plots showed that on increasing the LCLE concentration, the charge transfer resistance increased and the double layer capacitance decreased. The adsorption of LCLE on mild steel obeyed the Lang-muir adsorption isotherm. FT-IR, XRD, SEM and AFM techniques confirmed the adsorption of LCLE on mild steel surface. (C) 2013 Production and hosting by Elsevier B.V. on behalf of King Saud University.
引用
收藏
页码:S2343 / S2354
页数:12
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