Mild and efficient oxidation of alcohols with sodium periodate catalyzed by polystyrene-bound Mn(III)porphyrin

被引：62

作者：

Moghadam, M ^{[1
]}

Tangestaninejad, S

Mirkhani, V

Mohammadpoor-Baltork, I

Kargar, H

机构：

[1] Yasouj Univ, Dept Chem, Yasouj 75914353, Iran

[2] Isfahan Univ, Dept Chem, Esfahan 8174673441, Iran

来源：

BIOORGANIC & MEDICINAL CHEMISTRY | 2005年 / 13卷 / 08期

关键词：

alcohol; oxidation; supported; metalloporphyrin;

D O I：

10.1016/j.bmc.2005.02.012

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Mild and efficient oxidation of primary and secondary alcohols with sodium periodate catalyzed by Mn(TPyP), [manganese(III)tetra(4-pyridyl)porphyrin], supported on chloromethylated polystyrene, [Mn(TPyP)-CMP], at room temperature were reported. This catalyst can be reused consecutively four times in the oxidation of 4-chlorobenzyl alcohol in 97% yield without significant loss of its activity. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：2901 / 2905

页数：5

共 24 条

[1] Oxidation of α-alkylbenzyl alcohols catalysed by 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin iron(III) chloride.: Competition between C-H and C-C bond cleavage [J].