Syntheses, Crystal Structures and Properties of Zinc(II) and Co(II) Complexes Constructed by 2,2′-Dithiosalicylic Acid, Bis(2-carboxyphenyl) Sulfide and N-Donor Ligands

被引：5
作者：
Liu Ji-Wei [1 ]
机构：
[1] Northeast Petr Univ, Coll Chem & Chem Technol, Heilongjiang Prov Key Lab Oil & Gas Chem Technol, Daqing 163318, Heilongjiang, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 33卷 / 04期
关键词：
2.2 '-dithiosalicylic acid; bis(2-carboxyphenyl) sulfide; in situ reaction; crystal structure; COORDINATION POLYMERS;
D O I：
10.11862/CJIC.2017.068
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Zn(ll) complex. [Zn(C14H8O4S)(ip)(H2O)] (1) (C14H8O4S=bis(2-carboxyphenyl) sulfide, ip=1H-imidazo [4,5-f][1.10]phenanthroline) was prepared with 2,2'-dithiosalicylic acid, ip and Zn(NO3)(2) center dot 6H(2)O by in situ hydro thermal reaction; while f[Co(C14H8O4S2)(im)(2)]center dot H2O) (2) (C14H8O4S2=2,2'-dithiosalicylate, im=itnidazole) was synthesized by mixing 2.2'-dithiosalicylic acid, im and cobalt dinitrate; after that they were characterized by elemental analysis. thermal analysis, IR. fluorescent spectra analysis, XRD and X-ray single crystal diffraction. Complex 1 has a dinuclear structure, and the Zn(II) ion is five-coordinated in a distorted trigonal bipyramitlal geometry. Complex 2 has a one-dimensional chain structure, while the Co(Il) ion is six-coordinated to form a distorted octahedral configuration. CCDC: 998515, 1; 1002404, 2.
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页码：705 / 712
页数：8
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