Polystyrene beads modified with ester group and their application in n-heptane/toluene separation

被引:0
作者
Yu, Huan-yang [1 ]
机构
[1] Jilin Jianzhu Univ, Coll Mat Sci & Engn, Changchun 130118, Peoples R China
来源
ADVANCES IN TEXTILE ENGINEERING AND MATERIALS IV | 2014年 / 1048卷
关键词
swelling; polystyrene; separation; ester; LIQUID-LIQUID EQUILIBRIA; PLUS; MIXTURES; TEMPERATURE; MEMBRANES; SULFOLANE; GLYCOL;
D O I
10.4028/www.scientific.net/AMR.1048.423
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polystyrene beads modified with ester group for the separation of n-heptane/toluene have been successfully prepared. The synthesized beads were characterized by fourier transform infrared spectroscopy and thermogravimetric analysis. The effects of ester group on equillibrium swelling ratio and toluene selectivity were studied. The selective factor firstly increases then decreases with the increasing of ester group content. When the content of ester group is 30%, selective factor reaches maximum, the value is 1.62. Polystyrene beads modified with ester group show excellent thermal stability.
引用
收藏
页码:423 / 426
页数:4
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共 13 条
[1]   Liquid-liquid equilibria for n-alkanes (C12, C14, C17,) plus propylbenzene plus NMP mixtures at temperatures between 298 and 328 K [J].
Al-Jimaz, AS ;
Fandary, MS ;
Al-Kandary, JA ;
Fahim, MA .
FLUID PHASE EQUILIBRIA, 2005, 231 (02) :163-170
[2]   Liquid-liquid equilibrium for the systen heptane plus o-xylene plus diethylene glycol over the temperature range of 288.15 K to 318.15 K [J].
Ashour, I ;
Abdulkarim, MA .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (03) :924-927
[3]   CORRELATION OF THE PHASE-EQUILIBRIUM DATA FOR THE HEPTANE TOLUENE SULFOLANE AND HEPTANE XYLENE SULFOLANE SYSTEMS [J].
CASSELL, GW ;
HASSAN, MM ;
HINES, AL .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1989, 34 (04) :434-438
[4]   Isomorphously substituted B-MFI hollow fibre membranes for p-xylene separation from C8 aromatic mixtures [J].
Deng, Z. ;
Nicolas, C. -H. ;
Guo, Y. ;
Giroir-Fendler, A. ;
Pera-Titus, M. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2011, 80 (02) :323-329
[5]   Facile method of preparing silver-embedded polymer beads and their antibacterial effect [J].
Jun, Bong-Hyun ;
Byun, Jang-Woong ;
Kim, Jee Yeon ;
Kang, Homan ;
Park, Hee-Jin ;
Yoon, Jeyong ;
Lee, Yoon-Sik .
JOURNAL OF MATERIALS SCIENCE, 2010, 45 (11) :3106-3108
[6]   A novel atmospheric dielectric barrier discharge (DBD) plasma graft-filling technique to fabricate the composite membranes for pervaporation of aromatic/aliphatic hydrocarbons [J].
Li, Zhansheng ;
Zhang, Ben ;
Qu, Lianxu ;
Ren, Jizhong ;
Li, Yang .
JOURNAL OF MEMBRANE SCIENCE, 2011, 371 (1-2) :163-170
[7]   Influence of the temperature on the liquid-liquid equilibria of heptane plus toluene plus sulfolane and heptane plus m-xylene plus sulfolane [J].
Lin, Wen-Churng ;
Tsai, Teh-Hua ;
Lin, Thong-Yueh ;
Yang, Chien-Hsin .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (03) :760-764
[8]   Separation of benzene/cyclohexane mixture using semifluorinated aromatic poly(ether amide) membranes with and without cardo unit in the main chain [J].
Maji, Samarendra ;
Banerjee, Susanta ;
Pradhan, Narayan C. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2009, 70 (01) :128-135
[9]   Thermo-responsive polymer brush-grafted porous polystyrene beads for all-aqueous chromatography [J].
Mizutani, Aya ;
Nagase, Kenichi ;
Kikuchi, Akihiko ;
Kanazawa, Hideko ;
Akiyama, Yoshikatsu ;
Kobayashi, Jun ;
Annaka, Masahiko ;
Okano, Teruo .
JOURNAL OF CHROMATOGRAPHY A, 2010, 1217 (04) :522-529
[10]   Ternary liquid-liquid equilibra for pseudoternary mixtures containing an n-alkane plus an aromatic hydrocarbon plus {N-methyl-2-pyrrolidinone plus a solvent} at 298.2 K and 1 atm [J].
Naidoo, RD ;
Letcher, TM ;
Ramjugernath, D .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2001, 46 (06) :1375-1380