Lithium Recovery from Challenging Deposits: Zinnwaldite and Magnesium-Rich Salt Lake Brines

被引:23
作者
Bertau, Martin [1 ]
Voigt, Wolfgang [2 ]
Schneider, Anke [2 ]
Martin, Gunther [1 ]
机构
[1] Gunther Martin Freiberg Univ Min & Technol, Inst Chem Technol, Leipziger Str 29, D-09599 Freiberg, Germany
[2] Anke Schneider Freiberg Univ Min & Technol, Inst Inorgan Chem, Leipziger Str 29, D-09599 Freiberg, Germany
关键词
Lithium; Lithium carbonate; Salt lake brine; Zinnwaldite;
D O I
10.1002/cben.201700011
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Lithium can be found in its bound form in silicatic rocks and dissolved in salt lake brines. Both types of lithium resources, whose amounts exceed the expected demand for lithium by several times, are used for lithium recovery. The known lithium resources and their geochemical characteristics are reviewed together with the presently applied recovery processes which are still very similar to the historically early techniques. New processes for direct carbonization of zinnwaldite, hydrochloric and oxalic acid leaching as well as a new method for the recovery of lithium from magnesium-rich brines are presented.
引用
收藏
页码:360 / 376
页数:17
相关论文
共 86 条
[1]  
Jaffe R., Et al., Energy Critical Elements Securing Materials for Emerging Technologies, American Physical Society, (2011)
[2]  
Report on Critical Raw Material for the EU Non-Critical Raw Materials Profiles, European Commission, (2014)
[3]  
Frohlich P., Lorenz T., Martin G., Brett B., Bertau M., Angew. Chem. Int. Ed., 56, 10, pp. 2544-2580, (2017)
[4]  
Martin G., Rentsch L., Hock M., Bertau M., Energ. Storage Mater., 6, pp. 171-179, (2017)
[5]  
Ebensperger A., Maxwell P., Moscoso C., Resour. Policy, 30, 3, pp. 218-231, (2005)
[6]  
Naumov A.V., Naumova M.A., Russ. J. Non-Ferrous Met., 51, 4, pp. 324-330, (2010)
[7]  
Jaskula B.W., Mineral Commodity Summaries, (2016)
[8]  
Spencer E., Cobalt and Lithium the Winners in Battery Demand, (2016)
[9]  
Grosjean C., Miranda P.H., Perrin M., Poggi P., Renewable Sustainable Energy Rev., 16, 3, pp. 1735-1744, (2012)
[10]  
Bundesanstalt für Geowissenschaften und Rohstoffe, (2016)