Eu8(NCN)5-δI6+2δ (δ=0.05):: a novel rare-earth carbodiimide iodide containing oligomeric tritetrahedral Eu8 clusters

被引：5

作者：

Liao, WP ^{[1
]}

Fokwa, BPT ^{[1
]}

Dronskowski, R ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 28期

关键词：

D O I：

10.1039/b504235f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Eu-8(NCN)(4.95)I-6.10 is the first compound with discrete tritetrahedral Eu-8 clusters which are interconnected by coordinating NCN2- carbodiimide anions on their triangular faces to form separated layers, the latter being bridged by iodide and carbodiimide anions.

引用

页码：3612 / 3614

页数：3

共 38 条

[21] The first reduced rare earth halide with a group 11 element as interstitial:: La3I3Au [J].

Mattausch, H ;

Zheng, C ;

Kienle, L ;

Simon, A .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2004, 630 (13-14) :2367-2372

[22] B and B-C as interstitials in reduced rare earth halides [J].

Mattausch, H ;

Oeckler, O ;

Simon, A .

INORGANICA CHIMICA ACTA, 1999, 289 (1-2) :174-190

[23] SYNTHESIS OF NUCLEAR WASTE MONAZITES, IDEAL ACTINIDE HOSTS FOR GEOLOGIC DISPOSAL [J].

MCCARTHY, GJ ;

WHITE, WB ;

PFOERTSCH, DE .

MATERIALS RESEARCH BULLETIN, 1978, 13 (11) :1239-1245

[24] REDUCED HALIDES OF THE RARE-EARTH ELEMENTS [J].

MEYER, G .

CHEMICAL REVIEWS, 1988, 88 (01) :93-107

[25] Rare-earth diiodides and derivatives [J].

Meyer, G ;

Gerlitzki, N ;

Hammerich, S .

JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 380 (1-2) :71-78

[26]

Rissouli K, 1997, EUR J SOL STATE INOR, V34, P221

[27]

Schafer H., 1964, Angew. Chem., V76, P833, DOI [DOI 10.1002/ANGE.19640762002, 10.1002/ange.19640762002, DOI 10.1002/ANGE.196407622002]

[28] SYNTHESIS AND CHARACTERIZATION OF K3MO14O22, K1.66PB1.34MO14O22, AND K1.29SN1.71MO14O22 - OLIGOMERIC CLUSTERS WITH 3 TRANS EDGE-SHARED MO OCTAHEDRA [J].

SCHIMEK, GL ;

CHEN, SC ;

MCCARLEY, RE .

INORGANIC CHEMISTRY, 1995, 34 (24) :6130-6140

[29]

Schleid T, 1996, EUR J SOL STATE INOR, V33, P227

[30]

SHELDRICK GM, SHELXS SHELXL COMPUT

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