Eu8(NCN)5-δI6+2δ (δ=0.05):: a novel rare-earth carbodiimide iodide containing oligomeric tritetrahedral Eu8 clusters

被引:5
作者
Liao, WP [1 ]
Fokwa, BPT [1 ]
Dronskowski, R [1 ]
机构
[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany
关键词
D O I
10.1039/b504235f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Eu-8(NCN)(4.95)I-6.10 is the first compound with discrete tritetrahedral Eu-8 clusters which are interconnected by coordinating NCN2- carbodiimide anions on their triangular faces to form separated layers, the latter being bridged by iodide and carbodiimide anions.
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页码:3612 / 3614
页数:3
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