SESQUITERFENES FROM THE SEEDS OF Guarea guidonia (MELIACEAE)

被引:13
作者
Soares, Luzinatia Ramos [1 ,2 ]
de Queiroz e Silva, Alene Cortes [1 ]
Freire, Talita Vilalva [1 ]
Garcez, Fernanda Rodrigues [1 ]
Garcez, Walmir Silva [1 ]
机构
[1] Univ Fed Mato Grosso do Sul, Dept Quim, BR-79070900 Campo Grande, MS, Brazil
[2] Univ Estadual Mato Grosso Sul, Unidade Univ Coxim, BR-79400000 Coxim, MS, Brazil
来源
QUIMICA NOVA | 2012年 / 35卷 / 02期
关键词
Guarea guidonia; Meliaceae; eudesmane; SESQUITERPENES; DITERPENES; LEAVES; L;
D O I
10.1590/S0100-40422012000200017
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
SESQUITERFENES FROM THE SEEDS OF Guarea guidonia (MELIACEAE). Two new sesquiterpenes 6 alpha-ethoxyeudesm 15)-en-1 beta-ol (1) and (7R*)-5-epi-opposit-4(15)-ene-1 beta,7-diol (6), were isolated from the seeds of a specimen of Guarea guidonia (Meliaceae). Five other known sesquiterpenes, eudesm-4(15)-ene-1 beta,6 alpha-diol (2), 5-epi-euclesm-4(15)-ene-1 beta,6 beta-diol (3), eudesm-4(15)-ene-1 beta,5 alpha-diol (4), eudesm-4(15),7-dien-1 beta-ol (5) and (7R*)-opposit-4(15)-ene-1 beta,7-diol (6), were also isolated in this work. Their structures were determined on the basis of spectral data (MS. IR. and NMR-1D and 2D) and subsequent comparisons with the literature. The substances 3, 4 and 6 are reported for the first time in Meliaceae and 5 for the first time in the genus Guarea.
引用
收藏
页码:323 / 326
页数:4
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