Complexes of 4,5-diazafluorene and 9,9′-bis(4,5-diazafluorenyl) with nickel(II), copper(II) and zinc(II)

被引：12

作者：

Baysal, A ^{[1
]}

Connor, JA ^{[1
]}

Wallis, JD ^{[1
]}

机构：

[1] Univ Kent, Dept Chem, Sch Phys Sci, Canterbury CT2 7NJ, Kent, England

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2001年 / 53卷 / 04期

关键词：

copper; nickel; zinc; heterocycle; diazafluorenes;

D O I：

10.1080/00958970108022621

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes having the compositions [LMCl2], [L2MCl2], [L2Cu][PF6], [L ' MCl2] and [L ' (MCl2)(2)] of 4,5-diazafluorene, L, and 9,9 ' -bis(4,5-diazafluorenyl), L ', have been prepared from MCl2 (M=Ni, Cu, Zn) and characterised. Steric strain or the bite angle of the pro-ligand has no recognisable effect on its coordination chemistry with smaller 3d-metals.

引用

页码：347 / 354

页数：8

共 14 条

[1] BIS(2,2'-BIPYRIDYL)DIISOPROPOXYMOLYBDENUM(II) - STRUCTURAL AND SPECTROSCOPIC EVIDENCE FOR MOLYBDENUM-TO-BIPYRIDYL PI-STAR BONDING [J].