A study of the active species in the cationic polymerization initiated by AlCl3 complexes

被引：0

作者：

Butufei, O ^{[1
]}

Mazare, M ^{[1
]}

Miritescu, C ^{[1
]}

机构：

[1] ICECHIM, Inst Rech Chim Bucarest, Bucharest 76250, Romania

来源：

REVUE ROUMAINE DE CHIMIE | 2000年 / 45卷 / 12期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalysts of AlCl3 complexed with n-, i-, s-, t-butyl alcohols or with butyl chloride in toluene were synthesised at room temperature, at different molar ratios of the components. The dissolution of AlCl3, and the stability in time of the formed complexes was studied. The examination of the IR and IH-NMR spectra emphasized the presence in the AlCl3 complexes of the active species: Bu+AlCl3OH- toluene, Bu+AlCl4- toluene and [GRAPHICS] as well as the influence of the side reactions of esterification, hydrolysis and alkylation.

引用

页码：1079 / 1087

页数：9

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