Potential rhodium and ruthenium carbonyl complexes of phosphine-chalcogen (P-O/S/Se) donor ligands and catalytic applications

被引：56

作者：

Dutta, Dipak Kumar ^{[1
]}

Deb, Biswajit ^{[1
]}

机构：

[1] CSIR, Div Mat Sci, NE Inst Sci & Technol, Jorhat 785006, Assam, India

来源：

COORDINATION CHEMISTRY REVIEWS | 2011年 / 255卷 / 15-16期

关键词：

Rhodium; Ruthenium; Phosphine-chalcogen; Carbonylation; Hydrogenation; Hydroformylation; ASYMMETRIC TRANSFER HYDROGENATION; TRANSITION-METAL-COMPLEXES; BIS-PHOSPHORUS LIGANDS; X-RAY-STRUCTURE; AQUEOUS-BIPHASIC HYDROFORMYLATION; DITHIOLATO-BRIDGED RHODIUM; COORDINATION CHEMISTRY; HOMOGENEOUS CATALYSIS; OXIDATIVE ADDITION; STRUCTURAL-CHARACTERIZATION;

D O I：

10.1016/j.ccr.2011.01.025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review reports several types of potential metals (rhodium and ruthenium) carbonyl complexes of functionalized phosphine-chalcogen donors ligands like: P-X (X = O, S, Se) and their catalytic applications particularly in (i) carbonylation of alcohols, (ii) hydrogenation of unsaturated substrates and (iii) hydroformylation of alkenes for industrially important organic molecules. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：1686 / 1712

页数：27

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