Regioregular poly(p-alkoxyphenylene)s prepared from facile solid-state oxidative coupling polymerization

被引：20

作者：

Bai, WB ^{[1
]}

Zhan, CM ^{[1
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

来源：

CHEMISTRY LETTERS | 2005年 / 34卷 / 07期

关键词：

D O I：

10.1246/cl.2005.924

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By grinding 1,4-dialkoxybenzene with anhydrous FeCl3 powder using a glass pestle in a mortar at ambient and solvent-free condition, poly(p-phenylene)s (PPP) was obtained in high yield up to 90% in 30 min. The products were characterized by H-1 NMR, C-13 NMR, WAXD, and UV-vis and the regioregular structure was suggested. The solid-state oxidative coupling polymerization is a facile, time saving, "green-chemistry" method.

引用

页码：924 / 925

页数：2

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