Carbon nanosphere supported Ru catalyst for the synthesis of renewable herbicide and chemicals

被引：13

作者：

Gupta, Dinesh ^{[1
,2
]}

Saha, Basudeb ^{[2
,3
]}

机构：

[1] Indian Inst Technol Delhi, Dept Chem, Delhi, India

[2] Univ Delhi, Dept Chem, Lab Catalysis, Delhi 110007, India

[3] Univ Delaware, Dept Chem & Biomol Engn, Catalysis Ctr Energy Innovat, Newark, DE 19716 USA

来源：

CATALYSIS COMMUNICATIONS | 2017年 / 100卷

关键词：

Carbon sphere; Carbonaceous; Hydrogenation; 5-Aminolevulinic acid; gamma-valerolactone; DELTA-AMINOLEVULINIC-ACID; 5-AMINOLEVULINIC ACID; LEVULINIC ACID; GAMMA-VALEROLACTONE; BIOMASS; HYDROGENATION; SPHERES; NANOPARTICLES; GROWTH; PLANTS;

D O I：

10.1016/j.catcom.2017.07.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A carbon nanosphere supported Ru (Ru-CNS) effectively catalyzed the conversion of biorenewable platform chemicals to 5-aminoleulininc acid (ALA), furan alcohols and gamma-valerolactone (GVL). The catalyst exhibits high activity for the investigated processes, enabling 76% ALA and > 90% furan alcohols and GVL from their precursors. The effect of solvent polarity on the yield and selectivity of GVL and its ring-opening product has been studied with detailed characterization of the catalyst.

引用

页码：206 / 209

页数：4

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