Synthesis of Chiral Ionic Liquids from Natural Monosaccharides

被引:5
|
作者
Ghirardello, Mattia [1 ]
Costantini, Maira [2 ]
Vecchi, Alessandra [2 ]
Pacifico, Salvatore [2 ]
Pazzi, Daniele [2 ]
Castiglione, Franca [3 ]
Mele, Andrea [3 ]
Marra, Alberto [4 ]
机构
[1] Univ Bristol, Sch Chem, Cantocks Close, Bristol BS8 1TS, Avon, England
[2] Univ Ferrara, Dipartimento Sci Chim & Farmaceut, Via L Borsari 46, I-44121 Ferrara, Italy
[3] Politecn Milan, Dept Chem Mat & Chem Engn G Natta, Piazza L Da Vinci 32, I-20133 Milan, Italy
[4] Univ Montpellier, Inst Biomol Max Mousseron IBMM UMR 5247, POle Chim Balard Rech, 1919 Route Mende, F-34293 Montpellier 5, France
关键词
Benzimidazole; Carbohydrates; Imidazole; Ionic liquids; Pyrazole; SOLVENTS; SUGARS; ACIDS;
D O I
10.1002/ejoc.202200100
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Three series of new ionic liquids (ILs), namely imidazolium-, pyrazolium-, and bis-benzimidazolium-containing ILs, were prepared from low-cost, unprotected carbohydrates. Information on anion-cation interactions and solvation shell were obtained via diffusion NMR and heteronuclear Overhauser correlation maps (HOESY), respectively.
引用
收藏
页数:8
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