Two new self-penetrating metal-organic frameworks based on a flexible cyclohexanetetracarboxylate ligand

被引：15

作者：

Liu, Bo ^{[1
]}

Hou, Lei ^{[1
]}

Wang, Yao-Yu ^{[1
]}

Zhang, Ya-Nan ^{[1
]}

Cui, Lin ^{[1
]}

Shi, Qi-Zhen ^{[1
]}

机构：

[1] NW Univ Xian, Coll Chem & Mat Sci, Shaanxi Key Lab Physicoinorgan Chem, Key Lab Synthet & Nat Funct Mol Chem,Minist Educ, Xian 710069, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Metal-organic framework; Self-penetrating; Luminescence; Magnetic property; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; NETWORKS; CHEMISTRY; TOPOLOGY; SERIES; NETS;

D O I：

10.1016/j.inoche.2011.02.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new metal-organic frameworks, [M-2(CTA)(bipy)(1.5)(H2O)(2)](n)center dot 3n(H2O) (M=Cd for 1 and Mn for 2, H(4)CTA = cyclohexane-1,2,4,5-tetracarboxylic acid, bipy=4,4'-bipyridine) have been successfully synthesized and characterized. Complexes 1 and 2 are isostructural, which display unusual three-dimensional (3D) self-penetrating coordination frameworks with 3-nodal (3,5,5)-connectivity and the Schlafli symbol of (4,6,8)(4(2),6(7),8)(4(3),6(3),8(3),9). Moreover, in solid state, complex 1 exhibits blue emission at ambient temperature. Magnetic measurement shows that there exist weak antiferromagnetic interactions in 2. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：822 / 825

页数：4

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