Effect on orthometallation of NHC palladium complexes toward the catalytic activity studies in Suzuki coupling reaction

被引：27

作者：

Chen, Ming-Tsz ^{[1
]}

Kao, Zing-Lun ^{[1
]}

机构：

[1] Providence Univ, Dept Appl Chem, Taichung 43301, Taiwan

来源：

DALTON TRANSACTIONS | 2017年 / 46卷 / 47期

关键词：

N-HETEROCYCLIC CARBENE; ORTHO-SUBSTITUTED BIARYLS; ARYL CHLORIDES; ROOM-TEMPERATURE; C-N; (NHC)PD(ALLYL)CL NHC; AEROBIC CONDITIONS; ARYLBORONIC ACIDS; HIGHLY EFFICIENT; BOND FORMATION;

D O I：

10.1039/c7dt03280c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein, we report an approach to improve catalytic activity for cross-coupling reactions. N-Heterocyclic carbene (NHC) palladium complexes bearing a nitrogen-based ligand without orthometallation complexes show remarkable activities in Suzuki coupling reaction than orthometallation. Aryl chlorides examples employed in air and ambient temperature in Suzuki coupling reaction to reach completion within few minutes.

引用

页码：16394 / 16398

页数：5

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