Conversion of fructose and glucose into 5-hydroxymethylfurfural with lignin-derived carbonaceous catalyst under microwave irradiation in dimethyl sulfoxide-ionic liquid mixtures

被引：154

作者：

Guo, Feng ^{[1
]}

Fang, Zhen ^{[1
]}

Zhou, Tie-Jun ^{[1
]}

机构：

[1] Chinese Acad Sci, Biomass Grp, Lab Trop Plant Resource Sci, Xishuangbanna Trop Bot Garden, Kunming 650223, Yunnan, Peoples R China

来源：

BIORESOURCE TECHNOLOGY | 2012年 / 112卷

关键词：

5-Hydroxymethylfurfural; Fructose; Glucose; DMSO-[BMIM][Cl; Lignin; SOLID ACID CATALYST; EFFICIENT PRODUCTION; AMORPHOUS-CARBON; SUGAR CATALYST; DEHYDRATION; CELLULOSE; BIODIESEL; HYDROLYSIS; CHEMICALS; CHEMISTRY;

D O I：

10.1016/j.biortech.2012.02.108

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

5-Hydroxymethylfurfural (5-HMF) was successfully produced by the dehydration of fructose and glucose using lignin-derived solid acid catalyst in DMSO-[BMIM][Cl] (dimethyl sulfoxide and 1-butyl-3-methylimidazolium chloride) mixtures. Six solid acid catalysts were synthesized by carbonization and sulfonation of raw biomass materials, i.e., glucose, fructose, cellulose, lignin, bamboo and Jatropha hulls. It was found that lignin-derived solid acid catalyst (LCC) was the most active one in the dehydration of sugars. LCC coupled with microwave irradiation was used for the 5-HMF production, 84% 5-HMF yield with 98% fructose conversion rate was achieved at 110 degrees C for 10 min. Furthermore, 99% glucose was converted with 68% 5-HMF yield under severer condition (160 degrees C for 50 min). LCC was recycled for five times, 5-HMF yield declined only 7%. Use of LCC combined with DMSO-[BMIM][Cl] solution and microwave irradiation is a novel method for the effective production of 5-HMF. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：313 / 318

页数：6

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