Commercial activated carbon for the catalytic production of hydrogen via the sulfur-Iodine thermochemical water splitting cycle

被引：15
|
作者：
Ginosar, Daniel M. [1 ]
Petkovic, Lucia M. [1 ]
Burch, Kyle C. [1 ]
机构：
[1] Idaho Natl Lab, Idaho Falls, ID 83415 USA
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2011年 / 36卷 / 15期
关键词：
Thermochemical water splitting; Sulfur-iodine cycle; Hydroiodic acid decomposition; Hydrogen production; Activated carbon catalyst; CERIA CATALYSTS; DECOMPOSITION; KINETICS;
D O I：
10.1016/j.ijhydene.2011.04.164
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Eight commercial activated carbon catalysts were examined for their catalytic activity to decompose hydroiodic acid (HI) to produce hydrogen; a key reaction in the sulfur-iodine (S-I) thermochemical water splitting cycle. Activity was examined under a temperature ramp from 473 to 773 K. No statistically significant correlation was found between the measured catalyst sample properties and catalytic activity. Four of the eight samples were examined for one week of continuous operation at 723 K. All samples appeared to be stable over the period of examination. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：8908 / 8914
页数：7
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