Thermodynamics of adsorption on microporous adsorbents above critical temperatures

被引：17

作者：

Tolmachev, A. M. ^{[1
]}

Kuznetsova, T. A. ^{[1
]}

Godovikov, I. A. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

来源：

PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES | 2011年 / 47卷 / 03期

关键词：

VAPOR ADSORPTION; GASES;

D O I：

10.1134/S2070205111030178

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

The possibility of describing the isotherms of adsorption on microporous adsorbents at supercritical temperatures using the Dubinin-Radushkevich, Dubinin-Astakhov, and Tolmachev-Aranovich equations, in which the adsorbtive saturated vapor pressures that serve as the standard pressures below critical temperatures are substituted for the standard pressures (P (s) (*) ) found by the linear extrapolation of the dependences of adsorbtive saturated vapor pressure on the inverse temperature to the supercritical region, is shown. The possibility of linear extrapolation is substantiated by the data of a numerical experiment.

引用

页码：281 / 285

页数：5

共 16 条

[1]

Aranovich G.L., COLLOID INTERFACE SC, V141, P30

[2]

Dubinin M.M., 1975, Progress in Surface and Membrane Science, DOI [10.1016/B978-0-12-571809-7.50006-1, DOI 10.1016/B978-0-12-571809-7.50006-1]

[3]

Dubinin M. M., 1971, IAN SSSR KH, P17

[4]

DUBININ MM, 1971, B ACAD SCI USSR CH+, P11

[5]

DUBININ MM, 1971, B ACAD SCI USSR CH+, P5

[6]

ONO S, 1963, MOLEKULYARNAYA TEORI

[7]

Sychev V.V., 1979, Thermodynamic Properties of Methane

[8]

[Толмачев А.М. Tolmachev A.M.], 2005, [Журнал физической химии, Russian Journal of Physical Chemistry, Zhurnal fizicheskoi khimii], V79, P952

[9] Theoretical calculation of the isotherms of adsorption on active coals using the molecular dynamics method [J].

Tolmachev, A. M. ;

Anuchin, K. M. ;

Kryuchenkova, N. G. ;

Fomkin, A. A. .

PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2011, 47 (02) :150-155

[10] Adsorption of gases, vapors, and solutions: II. Description and a priori calculations of adsorption equilibria [J].

Tolmachev, A. M. .

PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2010, 46 (03) :291-308

← 1 2 →