More hydra than Janus - Non-classical coordination modes in complexes of oligopyridine ligands

被引：46
作者：
Constable, Edwin C. [1 ]
Housecroft, Catherine E. [1 ]
机构：
[1] Univ Basel, Dept Chem, Basel, Switzerland
来源：
COORDINATION CHEMISTRY REVIEWS | 2017年 / 350卷
基金：
美国国家科学基金会; 欧洲研究理事会; 瑞士国家科学基金会;
关键词：
Ligand; 2,2'-Bipyridine; 1,10-Phenanthroline; 2,2':6',2"-Terpyridine; Oligopyridine; Cyclometallation; Hypodentate; Reactivity; FLUXIONAL BIDENTATE LIGAND; DINUCLEAR PLATINUM(II) DERIVATIVES; CAMBRIDGE STRUCTURAL DATABASE; DEUTERIUM-EXCHANGE REACTION; TRANSITION-METAL-COMPLEXES; CARBONYL HALIDE-COMPLEXES; LIGHT-EMITTING DEVICES; C-H FUNCTIONALIZATION; RAY CRYSTAL-STRUCTURE; DOT-PI-INTERACTIONS;
D O I：
10.1016/j.ccr.2017.06.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Oligopyridine ligands and the related compound 1,10-phenanthroline have played a critical role in the development of coordination chemistry. This class of ligands probably constitutes the most commonly adopted metal-binding scaffold used in supramolecular and nanoscale chemistry. The adoption of the oligopyridine metal-binding domain in such areas is often predicated upon the assumption that the ligands will adopt chelating polydentate bonding modes. This review highlights the fact that these ligands are a great deal more versatile than this assumption would suggest. In addition to the chelation, cyclometallated and hypodentate bonding modes are also commonly observed. (C) 2017 Elsevier B.V. All rights reserved.
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页码：84 / 104
页数：21
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