Rapid and highly selective conversion of biomass into value-added products in hydrothermal conditions: chemistry of acid/base-catalysed and oxidation reactions

被引：312
作者：
Jin, Fangming [1 ,2 ]
Enomoto, Heiji [2 ]
机构：
[1] Tongji Univ, Coll Environm Sci & Engn, State Key Lab Pollut Control & Resources Reuse, Shanghai 200092, Peoples R China
[2] Tohoku Univ, Grad Sch Environm Studies, Aoba Ku, Sendai, Miyagi 9808579, Japan
来源：
ENERGY & ENVIRONMENTAL SCIENCE | 2011年 / 4卷 / 02期
关键词：
SUPERCRITICAL WATER OXIDATION; WEIGHT CARBOXYLIC-ACIDS; FORMIC-ACID; LACTIC-ACID; WET OXIDATION; HIGH-TEMPERATURE; ALKALINE-DEGRADATION; CARBOHYDRATE BIOMASS; ACETIC-ACID; ELECTRICAL CONDUCTANCES;
D O I：
10.1039/c004268d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An overview of recent advances in research on selective conversion of carbohydrates into products with hydrothermal chemistry is given. Conversion methods tend to use acid- or base-catalysed reactions and oxidation reactions. Conversion products that can be selectively produced include acetic acid, formic acid, lactic acid, levulinic acid, 5-hydroxymethyl-2-furaldehyde (HMF) and 2-furaldehyde (2-FA). Future conversion paths and possible new products that can be formed with hydrothermal chemistry include aldol/reverse condensation, dehydration, benzilic acid rearrangement, keto-enol tautomerization, Lobry de Bruyn-Alberda van Ekenstein transformation and oxidation reactions.
引用
收藏
页码：382 / 397
页数：16
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