Synthesis and characterization of hydridoirida-β-diketones formed by the reaction of [{Ir(Cod)Cl}2] (Cod=1,5-cyclooctadiene) with o-(diphenylphosphino)benzaldehyde

被引：46
作者：
Garralda, MA
Hernández, R
Ibarlucea, L
Pinilla, E
Torres, MR
机构：
[1] Univ Basque Country, Fac Quim San Sebastian, San Sebastian 20080, Spain
[2] Univ Complutense, Fac Ciencias Quim, Dept Quim Inorgan, Lab Difracc Rayos X, E-28040 Madrid, Spain
来源：
ORGANOMETALLICS | 2003年 / 22卷 / 17期
关键词：
D O I：
10.1021/om0301278
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
( Ir(Cod)Cl}(2)(Cod = 1,5-cyclooctadiene) reacts with o-(diphenylphosphino)benzaldehyde (PPh2(o-C6H4CHO)) (Ir:P = 1:2) in methanol to give the hydridoirida-beta\-diketone complex [IrH{(PPh2(o-C6H4Co))(2)H}Cl] (1). The reactivity of 1 to afford neutral and cationic hydridoirida-beta-diketones is also discussed.
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页码：3600 / 3603
页数：4
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