A partially water-soluble cationic Mn(III)-salphen complex for catalytic epoxidation

被引：8
作者：
Abdolmaleki, Amir [1 ]
Malek-Ahmadi, Saeed [1 ]
机构：
[1] Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran
来源：
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 2011年 / 89卷 / 10期
关键词：
phase transfer; phenazinium salt; cationic Mn(111)-salphen complex; epoxidation; PHASE-TRANSFER CAPABILITY; ASYMMETRIC EPOXIDATION; ENANTIOSELECTIVE EPOXIDATION; NONFUNCTIONALIZED ALKENES; HYDROGEN-PEROXIDE; SALEN CATALYSTS; MN(III) SALEN; EPOXIDES; OXIRANES; OLEFINS;
D O I：
10.1139/V11-094
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Synthesis and application of new cationic Mn(III)-salphen complexes for catalytic epoxidation of olefins to epoxides in a homogeneous reaction media have been reported. The experimental data showed that the cationic salphen is more active than its neutral form. The acceleration of the reaction rate is attributed to the phase-transfer capability of the built-in phenazinium salt of the Mn(II)-salphen catalyst.
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页码：1202 / 1206
页数：5
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