Novel reactions of [2.2]paracyclophane-azomethines with benzyne

被引：14

作者：

Aly, AA

Mourad, AFE ^{[1
]}

El-Shaieb, KM

Hopf, H

机构：

[1] El Minia Univ, Fac Sci, Dept Chem, El Minia, Egypt

[2] Tech Univ Braunschweig, Inst Organ Chem, D-38106 Braunschweig, Germany

来源：

SYNTHETIC COMMUNICATIONS | 2001年 / 31卷 / 04期

关键词：

D O I：

10.1081/SCC-100000593

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Schiff bases 4-([2.2]paracyclophanylidine)-4-methyl-aniline (1), p-tolylidine-4[2.2] -paracyciophanyl amine (5) and piperonylidine-4[2.2]paracyclophanylamine (7) have been reacted with benzyne (2) to afford fused paracyclophenanthridinophane derivatives 3, 6, and 8, respectively. (4-[2.2]-Paracyclophanylidine) cyclohexylamine (9) reacted with three equivalents of benzyne; two undergoing ene-addition and one [4 + 2]cycloaddition to afford compound 10.

引用

页码：637 / 644

页数：8

共 17 条

[1] Reaction of diimines and benzyne [J].