Enantiomeric enrichment of a nonracemic conglomerate of a chiral oxo-rhenium(v) complex

被引：5

作者：

Rybak, WK ^{[1
]}

Skarzynska, A ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

NEW JOURNAL OF CHEMISTRY | 2003年 / 27卷 / 12期

关键词：

D O I：

10.1039/b308170b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The enantiomer being in excess was readily recovered from a nonracemic conglomerate of chiral cis-[ReOCl2{OCMe2CMe2O-P(OCMe2CMe2O)}py] by means of a difference in solubility between the enantiomer and the racemate; subsequently the solubility diagram and the specific optical rotation [a](589) = +1345 (+/-30 max. absolute error; c = 0.05 g per 100 cm(3) in MeCN) for the pure enantiomer of the absolute configuration C was also determined.

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页码：1687 / 1689

页数：3

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